[Article] Score tests of genetic association in the presence by Zhong X., Li H.

By Zhong X., Li H.

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There is a single report of the direct reaction between a metal, PF,, and hydrogen at elevated temperature and pressure (method D) to give a 97% yield of the desired hydrido complex (180). Co + PF, + H, - CoH(PF,), Transition metal carbonyl complexes can be suitable precursors, for example, treatment of hydrido complexes or their alkali salts with PF, under UV irradiation followed if necessary by acidification of the reaction mixture (method E). Interestingly, vanadium forms the hydrido trifluorophosphine complex [VH(PF,),], whereas with CO, the paramagnetic [V(CO),] is formed.

Chen, C. , and Liu, C. , J. Organomet. Chem. 226,21(1982). Paquin, D. , and Ring, M. , J. Am. Chem. 99,1793 (1977). Perry, D. , and Margrave, J. , J. Chem. Educ. 53,696 (1976). Purnell, J. , Proc. R. London, Ser. A . 293,543 (1966). 82. Reynolds, W. , Thompson, J. , and Wright, A. P. , Can. J. Chem. 58,419 (1980). 83. Reynolds, W. , Thompson, J. , and Wright, A. P. , Can. J. Chem. 58,425 (1980). 84. Ring, M. A,, Puentes, H. , and O’Neal, H. , J. Am. Chem. 92,4845 (1970). 85. Ring, M. , Beverly, G.

J. Fluorine Chem. 2,103 (1972). Pai, Y. , Chen, C. , and Liu, C. , J. Organomet. Chem. 226,21(1982). Paquin, D. , and Ring, M. , J. Am. Chem. 99,1793 (1977). Perry, D. , and Margrave, J. , J. Chem. Educ. 53,696 (1976). Purnell, J. , Proc. R. London, Ser. A . 293,543 (1966). 82. Reynolds, W. , Thompson, J. , and Wright, A. P. , Can. J. Chem. 58,419 (1980). 83. Reynolds, W. , Thompson, J. , and Wright, A. P. , Can. J. Chem. 58,425 (1980). 84. Ring, M. A,, Puentes, H. , and O’Neal, H. , J. Am. Chem.

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